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    Dimethyl carbonate

     

    Molecular formula: C3H6O3
    Structural formula:

    Relative Molecular weight: 90.08
    Class:3.2
    CAS No.: 616-38-6
    UN No.: 1161

    Specifications:

    Item Index
    Top class First class
    Appearance Colorless & transparent liquid Colorless & transparent liquid
    Content, % ≥99.9 ≥99.5
    Moisture, % ≤0.02 ≤0.1
    Methanol, % ≤0.02 ≤0.1
    Acidity, % ≤0.015 ≤0.015
    Free chlorine, % ≤0.01 ≤0.01
    Color,(APHA) ≤5 ≤10

    Packing:
    Packed in galvanized iron drums, net weight 200Kg/drum; or in ISO tank. Also can be packed according to the clients' requirement.

    Storage and transportation:
    Dimethyl Carbonate is combustible. If coming into contact with oxidization, it will burn. It should be stored in a cool and windy special warehouse far from fire and transported as a combustible chemical product.
     
    Applications of DMC:
    PC: DMC can be used to compound PC.

    Pharmacy: DMC is mainly used to compose antibiotics, fever-reliever and painkiller, vitamin and central nervous system depressants & stimulants.

    Pesticide: DMC is mainly used to produce methyl isocyanate and further produce some amino formic acid medicine, etc.

    Substitute: DMC can produce phenyl methyl ether by taking the place of dimethyl sulphate, and manufacture TMAH in place of chloromethane.

    DMC can produce ADC and Toluene diisocyanate by taking the place of toxic phosgene.
    Other fields:DMC can also be used in other fields such as solvent, dye and electrolyte, etc.

    Physical properties:

    Appearance Normal atmospheric temperature,
    water-like volatile liquid
    Scent Light sweet smell
    Density(d420) 1.073
    Melting point 4℃
    Boiling point 90.1(0.1MPa)
    Solution Minutely soluble in water but mixed with some organic solvent such as ether, alcohol and ketone,  etc.
    Flash point 21.7(open)  16.7(close)
    Index of refraction n20D =1.3687
    Heat of combustion 3452kcal/kg
    Solution in water of combustion 12.6wt%
    Water solution of combustion 2.9wt%
    RON 110
    MON 97
    Viscosity 0.664mPa.s
    Critical pressure 4.57MPa
    Critical temperature 539.0k
    Vaporization latent heat 8382kJ/kmol
    Dielectric constant 3.1c/v.m
    Wistar LD50=6400—12800mg/kg

    Some boiling point, Solubility Parameters, Relative Evaporation Rate between DMC and other organic solvent.

    Solvent boiling point /℃ Solubility Relative volatility
    Acetone 56.5 10 7.2
    Butanone 79.57 9.3 4.65
    Ethyl acetate 77.15 9 5.3
    Butyl acetate 126.5 8.5 1
    Toluene 110.6 8.9 1.95
    Xylene 135-145 8.8 0.68
    Dimethyl Carbonate 90.2 9.9 3.4

    Dimethyl Carbonate, as a green organic solvent with advanced performance, can substitute toluene, xylene, ethyl acetate, butyl acetate, acetone or butanone to produce environmental coating, adhesive and printing ink, etc.

     
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